National Standard of the People’s Republic of China
Ambient Air Quality Standard
(GB3095-1996)
1. Subject and Scope
This Standard stipulates the designation of functional areas of ambient air quality, standard classification, pollutants, sampling time and concentration limits, sampling and analyzing methods as well as the definition of validity of data statistics.
This Standard is applicable to the evaluation of countrywide ambient air quality.
2. Reference Standard
|
GB/T 15262 |
Air Quality |
Determination of sulfur dioxide — Formaldehyde absorbing- pararosaniline spectrophotometry |
|
GB 8970 |
Air Quality |
Determination of sulfur dioxide in ambient air—Tetrachloromercurate (TCM)-pararosaniline method |
|
GB/T 5432 |
Ambient Air |
Determination of total suspended particles — Gravimetric method |
|
GB6921 |
Air Quality |
Determination of the concentration of airborne particulate matters |
|
GB/T15436 |
Ambient Air |
Determination of nitrogen oxides — Saltzman method |
|
GB/T15435 |
Ambient Air |
Determination of nitrogen dioxides — Saltzman method |
|
GB/T15437 |
Ambient Air |
Determination of ozone — Indigo disulphonate spectrophotometry |
|
GB/T15438 |
Ambient Air |
Determination of ozone — Ultraviolet photometric method |
|
GB9801 |
Air Quality |
Determination of carbon monoxide — Non-dispersive infrared spectrometry |
|
GB8971 |
Air Quality |
Determination of Benzo[a]pyrene in flying dust — Acetylated paper chromatography fluoroscene spectrophotometric method |
|
GB/T15439 |
Ambient Air |
Determination of Benzo[a]pyrene in ambient air — High performance liquid chromatography |
|
GB/T15264 |
Air Quality |
Determination of lead—Flame atomic absorption spectrophotometric method |
|
GB/T15434 |
Ambient Air |
Determination of the mass concentration of fluoride — Method by filter sampling and fluorine ion-selective electrode analysis |
|
GB/T15433 |
Ambient Air |
Determination of the fluoride — Method by lime-paper sampling and fluorine ion-selective electrode analysis |
3. Definition
3.1 Total suspended particles (TSP): The particles that can be suspended in the air with an aerodynamic equivalent diameter ≤ 100 micrometer.
3.2 Breathable particles (PM10): The particles that can be suspended in the air with an aerodynamic equivalent diameter ≤ 10 micrometer.
3.3 Nitrogen oxide (as NO2): The nitrogen oxide existing in the air in the form of nitrogen monoxide and nitrogen dioxide.
3.4 Lead (Pb): The lead and its compounds existing in TSP.
3.5 Benzo[a]pyrene (B[a]P): The benzo[a]pyrene existing in breathable particles.
3.6 Fluoride (as F): Inorganic fluoride existing in gaseous and particulate states.
3.7 Annual average: The arithmetic mean of daily average concentration in any year.
3.8 Quarterly average: The arithmetic mean of daily average concentration in any quarter.
3.9 Monthly average: The arithmetic mean of daily average concentration in any month.
3.10 Daily average: The average concentration on any day.
3.11 Hourly average: The average concentration in any hour.
3.12 Average in plant growth season: The arithmetic mean of monthly average concentration in any plant growth season.
3.13 Ambient air: Outside air which human beings, plants, animals, and buildings are exposed to.
3.14 Normal state: The state at a temperature of 273K and a pressure of 101.325Kpa.
4. Grouping and Standard Classification of Functional Area of Ambient Air Quality
4.1 Grouping of functional area of ambient air quality
Group I area includes natural protection zones, scenic spots and other areas for which special protections are necessary.
Group II area includes the residential quarters designated in town planning, mixed areas of business, communication and living, cultural areas, normal industrial areas and rural areas.
Group III area includes specialized industrial areas.
4.2 Standard classification of ambient air quality
The standard of ambient air quality is classified as three classes.
Class 1 standard is imposed for Group I area.
Class 2 standard is imposed for Group II area.
Class 3 standard is imposed for Group III area.
5. Concentration Limit
This Standard stipulates the concentration limits of various pollutants that are not allowed to be exceeded. For the details, refer to the following table:
Table 1 - Concentration Limit for Various Pollutants
|
Pollutant |
Sampling time |
Concentration limit |
Unit of concentration |
|
Class 1 standard |
Class 2 standard |
Class 3 standard |
|
Sulfur dioxide SO2 |
Annual average
Daily average
Hourly average |
0.02
0.05 0.15 |
0.06
0.15
0.50 |
0.10
0.25
0.70 |
mg/m3
(normal state) |
|
Total suspended particles TSP |
Annual average
Daily average |
0.08
0.12 |
0.20
0.30 |
0.30
0.50 |
|
Breathable particles PM10 |
Annual average
Daily average |
0.04
0.05 |
0.10
0.15 |
0.15
0.25 |
|
Nitrogen oxide NOx |
Annual average
Daily average
Hourly average |
0.05
0.10
0.15 |
0.05
0.10
0.15 |
0.10
0.15
0.30 |
|
Nitrogen dioxide NO2 |
Annual average
Daily average
Hourly average |
0.04
0.08
0.12 |
0.04
0.08
0.12 |
0.08
0.12
0.24 |
|
Carbon monoxide CO |
Daily average
Hourly average |
4.00
10.00 |
4.00
10.00 |
6.00
20.00 |
|
Ozone O0 |
Hourly average |
0.12 |
0.16 |
0.20 |
|
Lead pb |
Quarterly average
Annual average |
1.50
1.00 |
mm/m3 (normal state) |
|
Benzo[a]
Pyrene B[a]P |
Daily average |
0.01 |
|
Fluoride
F |
Daily average
Hourly average |
7 ?
20? |
|
Fluoride
F |
Monthly average in plant growth season |
1.8
1.2
|
3.0 ?
2.0 ?
|
mm/(dm2/day) |
|
|
|
|
|
|
|
Note: ? is applicable to urban area; is applicable to pastoral area, agricultural-pastoral area in which priority is given to pastoral, silkworm breeding area; ? is applicable for agricultural area and forest zone.
6. Monitoring
6.1 Sampling
The requirements of sampling point, sampling environment, sampling attitude and frequency for monitoring the ambient air are executed in accordance with “Technical Specifications of Environment Monitoring” (Section: Atmosphere)
6.2 Analyzing Method
For the analyzing methods for various pollutants, refer to Table 2.
Table 2 - Analyzing methods for various pollutants
|
Pollutant |
Analyzing method |
Source
|
|
Sulfur dioxide |
(1) Formaldehyde absorbing-pararosaniline spectrophotometry
(2) Tetrachloromercurate (TCM)-pararosaniline method
(3) Ulraviolet photometric method ? |
GB/T15262-94
GB8970-88 |
|
Total suspended particles |
Gravimetric method |
GB/T15432-95 |
|
Breathable particles |
Gravimetric method |
GB6921-86 |
|
Nitrogen oxide
(as NO2) |
(1) Saltzman method
(2) Chemiluminescene |
GB/T15436-95 |
|
Nitrogen dioxide |
(1) Saltzman method
(2) Chemiluminescene |
GB/T15435-95 |
|
Ozone |
(1) Indigo disulphonate spectrophotometry
(2) Ultraviolet photometric method
(3) Chemiluminescene ? |
GB/T15437-95
GB/T15438-95 |
|
Carbon monoxide |
Non-dispersive infrared spectrometry |
GB9801-88 |
|
Benzo[a]pyrene |
(1) Acetylated paper chromatography fluorescene spectrophotometry
(2) High-performance liquid chromatography |
GB9871-88
GB/T15439-95 |
|
Lead |
Flame atomic absorption spectrophotometric method |
GB/T15264-94 |
|
Fluoride (as F) |
(1) Method by filter sampling and fluorine ion-selective electrode analysis ¯
(2) Method by lime-paper sampling and fluorine ion-selective electrode analysis ° |
GB/T15434-95
GB/T15433-95
|
Note: ISO/CD10498, ISO7996, ISO10313 are executed respectively for ?, and ? for the time being. Corresponding national standards will be implemented after their issuance; ¯ is used for daily average and hourly average; ° is used for monthly average and average in plant growth season.
7. Definition of Validity of Data Statistics
For definition of validity of data statistics, refer to Table 3.
Table 3 - Definition of Validity of Data Statistics for Various Pollutants
|
Pollutant |
Samplint time |
Definition of validity of data |
|
SO2, NOx, NO2 |
Annual average |
At least 144 evenly-distributed daily averages are available each year.
At least 12 evenly-distributed daily averages are available each month. |
|
TSP, PM10, pb |
Annual average |
At least 60 evenly-distributed daily averages are available each year.
At least 5 evenly-distributed daily averages are available each month. |
|
SO2, NOx, NO2 , CO |
Daily average |
At least 18 hours for sampling are available each day. |
|
TSP, PM10, B(a)P, pb |
Daily average |
At least 12 hours for sampling are availabe each day. |
|
SO2, NOx, NO2, CO, O3 |
Hourly average |
At least 45 minutes for sampling are available each hour. |
|
pb |
Quarterly average |
At least 15 evenly-distributed daily averages are available each quarter.
At least 5 evenly-distributed daily averages are available each month. |
|
F |
Monthly average |
At least 15 days for sampling are available each month. |
|
Average in plant growth season |
At least 70% of the monthly averages are available during each growth season. |
|
Daily average |
At least 12 hours for samling are available each day. |
|
Hourly average |
At least 45 minutes for sampling are available each hour. |
8. Implementation of Standard
8.1 The environemntal protection authorities at various levels are responsible for the supervision and implementation of this Standard.
8.2 This Standard stipulates the hourly, daily, monthly, quarterly and annual averages of concentration limits, however, the environemntal protection authorities at various levels shall supervise the implementation of this Standard based on different purposes.
8.3 The functional areas of ambient air quality are designated by the environemntal protection authorities of cities above the prefecture-level (including prefecture-level cities), and submitted to the people’s government of the same level for approval and implementation. |